Structural, Optical, and Transport Properties of ..alpha..- and ..beta...-Ag3VO4

V. Cloet; A. Raw; K. R. Poeppelmeier; G. Trimarchi; H. Peng; J. Im; A. J. Freeman; N. H. Perry; T. O. Mason; A. Zakutayev; P. F. Ndione; D. S. Ginley; J. D. Perkins

doi:10.1021/cm301119c

Structural, Optical, and Transport Properties of ..alpha..- and ..beta...-Ag3VO4

V. Cloet
, A. Raw
, K. R. Poeppelmeier
, G. Trimarchi
, H. Peng
, J. Im
, A. J. Freeman
, N. H. Perry
, T. O. Mason
, A. Zakutayev
, P. F. Ndione
, D. S. Ginley
, J. D. Perkins

Northwestern University
National Renewable Energy Laboratory

Research output: Contribution to journal › Article › peer-review

37 Scopus Citations

Abstract

The structures of α- and β-Ag ₃VO ₄ were studied via single-crystal X-ray diffraction (XRD). The transition from α-phase to β-phase was found to occur at 110 °C. Single-crystal XRD revealed that the integrity of the single crystals was maintained as Ag ₃VO ₄ reversibly transitioned between α-Ag ₃VO ₄ and β-Ag ₃VO ₄. The optical and electrical properties of polycrystalline α-Ag ₃VO ₄ were studied by diffuse reflectance spectroscopy and impedance spectroscopy. In order to assess the optical and electrical properties of β-Ag ₃VO ₄, in situ measurements were performed above the phase-transition temperature. Thin films of α-Ag ₃VO ₄ were prepared by combinatorial sputtering and pulsed laser deposition (PLD). The crystallographic, optical, and electrical conductivity properties of the α-Ag ₃VO ₄ thin films were compared with the bulk properties.

Original language	American English
Pages (from-to)	3346-3354
Number of pages	9
Journal	Chemistry of Materials
Volume	24
Issue number	17
DOIs	https://doi.org/10.1021/cm301119c https://doi.org/10.1021/cm301119c
State	Published - 11 Sep 2012

NLR Publication Number

NREL/JA-5200-56826

Keywords

α-Ag VO
β-Ag VO
electrical conductivity
single crystal
thin film

Access to Document

Cite this

Cloet, V., Raw, A., Poeppelmeier, K. R., Trimarchi, G., Peng, H., Im, J., Freeman, A. J., Perry, N. H., Mason, T. O., Zakutayev, A., Ndione, P. F., Ginley, D. S., & Perkins, J. D. (2012). Structural, Optical, and Transport Properties of ..alpha..- and ..beta...-Ag3VO4. Chemistry of Materials, 24(17), 3346-3354. https://doi.org/10.1021/cm301119c, https://doi.org/10.1021/cm301119c

@article{b80aa08ed7574a9396db4a963b0cb30b,

title = "Structural, Optical, and Transport Properties of ..alpha..- and ..beta...-Ag3VO4",

abstract = "The structures of α- and β-Ag 3VO 4 were studied via single-crystal X-ray diffraction (XRD). The transition from α-phase to β-phase was found to occur at 110 °C. Single-crystal XRD revealed that the integrity of the single crystals was maintained as Ag 3VO 4 reversibly transitioned between α-Ag 3VO 4 and β-Ag 3VO 4. The optical and electrical properties of polycrystalline α-Ag 3VO 4 were studied by diffuse reflectance spectroscopy and impedance spectroscopy. In order to assess the optical and electrical properties of β-Ag 3VO 4, in situ measurements were performed above the phase-transition temperature. Thin films of α-Ag 3VO 4 were prepared by combinatorial sputtering and pulsed laser deposition (PLD). The crystallographic, optical, and electrical conductivity properties of the α-Ag 3VO 4 thin films were compared with the bulk properties.",

keywords = "α-Ag VO, β-Ag VO, electrical conductivity, single crystal, thin film",

author = "V. Cloet and A. Raw and Poeppelmeier, \{K. R.\} and G. Trimarchi and H. Peng and J. Im and Freeman, \{A. J.\} and Perry, \{N. H.\} and Mason, \{T. O.\} and A. Zakutayev and Ndione, \{P. F.\} and Ginley, \{D. S.\} and Perkins, \{J. D.\}",

year = "2012",

month = sep,

day = "11",

doi = "10.1021/cm301119c",

language = "American English",

volume = "24",

pages = "3346--3354",

journal = "Chemistry of Materials",

issn = "0897-4756",

publisher = "American Chemical Society",

number = "17",

}

TY - JOUR

T1 - Structural, Optical, and Transport Properties of ..alpha..- and ..beta...-Ag3VO4

AU - Cloet, V.

AU - Raw, A.

AU - Poeppelmeier, K. R.

AU - Trimarchi, G.

AU - Peng, H.

AU - Im, J.

AU - Freeman, A. J.

AU - Perry, N. H.

AU - Mason, T. O.

AU - Zakutayev, A.

AU - Ndione, P. F.

AU - Ginley, D. S.

AU - Perkins, J. D.

PY - 2012/9/11

Y1 - 2012/9/11

N2 - The structures of α- and β-Ag 3VO 4 were studied via single-crystal X-ray diffraction (XRD). The transition from α-phase to β-phase was found to occur at 110 °C. Single-crystal XRD revealed that the integrity of the single crystals was maintained as Ag 3VO 4 reversibly transitioned between α-Ag 3VO 4 and β-Ag 3VO 4. The optical and electrical properties of polycrystalline α-Ag 3VO 4 were studied by diffuse reflectance spectroscopy and impedance spectroscopy. In order to assess the optical and electrical properties of β-Ag 3VO 4, in situ measurements were performed above the phase-transition temperature. Thin films of α-Ag 3VO 4 were prepared by combinatorial sputtering and pulsed laser deposition (PLD). The crystallographic, optical, and electrical conductivity properties of the α-Ag 3VO 4 thin films were compared with the bulk properties.

AB - The structures of α- and β-Ag 3VO 4 were studied via single-crystal X-ray diffraction (XRD). The transition from α-phase to β-phase was found to occur at 110 °C. Single-crystal XRD revealed that the integrity of the single crystals was maintained as Ag 3VO 4 reversibly transitioned between α-Ag 3VO 4 and β-Ag 3VO 4. The optical and electrical properties of polycrystalline α-Ag 3VO 4 were studied by diffuse reflectance spectroscopy and impedance spectroscopy. In order to assess the optical and electrical properties of β-Ag 3VO 4, in situ measurements were performed above the phase-transition temperature. Thin films of α-Ag 3VO 4 were prepared by combinatorial sputtering and pulsed laser deposition (PLD). The crystallographic, optical, and electrical conductivity properties of the α-Ag 3VO 4 thin films were compared with the bulk properties.

KW - α-Ag VO

KW - β-Ag VO

KW - electrical conductivity

KW - single crystal

KW - thin film

UR - https://www.scopus.com/pages/publications/84866064302

U2 - 10.1021/cm301119c

DO - 10.1021/cm301119c

M3 - Article

AN - SCOPUS:84866064302

SN - 0897-4756

VL - 24

SP - 3346

EP - 3354

JO - Chemistry of Materials

JF - Chemistry of Materials

IS - 17

ER -

Structural, Optical, and Transport Properties of ..alpha..- and ..beta...-Ag3VO4

Abstract

NLR Publication Number

Keywords

Access to Document

Other files and links

Fingerprint

Cite this