Photoelectrochemical Characterization of Several Semiconducting Compounds of Palladium with Sulfur and/or Phosphorus

J. C.W. Folmer; J. A. Turner; B. A. Parkinson

doi:10.1016/0022-4596(87)90281-7

Photoelectrochemical Characterization of Several Semiconducting Compounds of Palladium with Sulfur and/or Phosphorus

J. C.W. Folmer
, J. A. Turner
, B. A. Parkinson

Chemistry and Nanoscience

National Renewable Energy Laboratory

Research output: Contribution to journal › Article › peer-review

47 Scopus Citations

Abstract

Semiconducting compounds of palladium with sulfur and/or phosphorus were prepared as crystals and their semiconducting and photoelectrochemical properties studied. The compounds include PdS, PdPS, Pd₃(PS₄)₂, and PdP₂ and crystal growth was accomplished by chemical vapor transport with halogens and Bridgeman methods. Photoelectrochemical techniques were used to measure bandgap, transition type, doping level, majority carrier type, flatband potential, quantum yield for electron flow, and stability in a photoelectrochemical cell. The previously undetermined bandgap of PdP₂ is reported (1.08 eV, indirect).

Original language	American English
Pages (from-to)	28-37
Number of pages	10
Journal	Journal of Solid State Chemistry
Volume	68
Issue number	1
DOIs	https://doi.org/10.1016/0022-4596(87)90281-7 https://doi.org/10.1016/0022-4596(87)90281-7
State	Published - 1987

NLR Publication Number

ACNR/JA-236-9521

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title = "Photoelectrochemical Characterization of Several Semiconducting Compounds of Palladium with Sulfur and/or Phosphorus",

abstract = "Semiconducting compounds of palladium with sulfur and/or phosphorus were prepared as crystals and their semiconducting and photoelectrochemical properties studied. The compounds include PdS, PdPS, Pd3(PS4)2, and PdP2 and crystal growth was accomplished by chemical vapor transport with halogens and Bridgeman methods. Photoelectrochemical techniques were used to measure bandgap, transition type, doping level, majority carrier type, flatband potential, quantum yield for electron flow, and stability in a photoelectrochemical cell. The previously undetermined bandgap of PdP2 is reported (1.08 eV, indirect).",

author = "Folmer, \{J. C.W.\} and Turner, \{J. A.\} and Parkinson, \{B. A.\}",

year = "1987",

doi = "10.1016/0022-4596(87)90281-7",

language = "American English",

volume = "68",

pages = "28--37",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

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T1 - Photoelectrochemical Characterization of Several Semiconducting Compounds of Palladium with Sulfur and/or Phosphorus

AU - Folmer, J. C.W.

AU - Turner, J. A.

AU - Parkinson, B. A.

PY - 1987

Y1 - 1987

N2 - Semiconducting compounds of palladium with sulfur and/or phosphorus were prepared as crystals and their semiconducting and photoelectrochemical properties studied. The compounds include PdS, PdPS, Pd3(PS4)2, and PdP2 and crystal growth was accomplished by chemical vapor transport with halogens and Bridgeman methods. Photoelectrochemical techniques were used to measure bandgap, transition type, doping level, majority carrier type, flatband potential, quantum yield for electron flow, and stability in a photoelectrochemical cell. The previously undetermined bandgap of PdP2 is reported (1.08 eV, indirect).

AB - Semiconducting compounds of palladium with sulfur and/or phosphorus were prepared as crystals and their semiconducting and photoelectrochemical properties studied. The compounds include PdS, PdPS, Pd3(PS4)2, and PdP2 and crystal growth was accomplished by chemical vapor transport with halogens and Bridgeman methods. Photoelectrochemical techniques were used to measure bandgap, transition type, doping level, majority carrier type, flatband potential, quantum yield for electron flow, and stability in a photoelectrochemical cell. The previously undetermined bandgap of PdP2 is reported (1.08 eV, indirect).

UR - https://www.scopus.com/pages/publications/0023344169

U2 - 10.1016/0022-4596(87)90281-7

DO - 10.1016/0022-4596(87)90281-7

M3 - Article

AN - SCOPUS:0023344169

SN - 0022-4596

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EP - 37

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

IS - 1

ER -

Photoelectrochemical Characterization of Several Semiconducting Compounds of Palladium with Sulfur and/or Phosphorus

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