Optoelectronic Characterization of Emerging Solar Absorber Cu3AsS4

Patricia Dippo; Darius Kuciauskas; Scott McClary; Siming Li; Xinxing Yin; Yanfa Yan; Jason Baxter; Rakesh Agrawal

doi:10.1109/PVSC40753.2019.8980590

Optoelectronic Characterization of Emerging Solar Absorber Cu3AsS4

Patricia Dippo
, Darius Kuciauskas
, Scott McClary
, Siming Li
, Xinxing Yin
, Yanfa Yan
, Jason Baxter
, Rakesh Agrawal

Purdue University
Drexel University
University of Toledo

Research output: Contribution to conference › Paper › peer-review

10 Scopus Citations

Abstract

Enargite Cu₃AsS₄ is a promising absorber for thin-film solar cells but little is known about its optoelectronic properties. Here, we present photoluminescence (PL) spectroscopy, time-resolved terahertz spectroscopy (TRTS), timeresolved photoluminescence (TRPL) spectroscopy, and cyclic voltammetry (CV) measurements of enargite thin films. The results indicate promising defect characteristics with minority carrier lifetimes on the order of ns, and band alignments suggest that buffer layers besides CdS must be developed to achieve high efficiency Cu₃AsS₄ solar cells.

Original language	American English
Pages	2310-2314
Number of pages	5
DOIs	https://doi.org/10.1109/PVSC40753.2019.8980590 https://doi.org/10.1109/PVSC40753.2019.8980590
State	Published - Jun 2019
Event	46th IEEE Photovoltaic Specialists Conference, PVSC 2019 - Chicago, United States Duration: 16 Jun 2019 → 21 Jun 2019

Conference

Conference	46th IEEE Photovoltaic Specialists Conference, PVSC 2019
Country/Territory	United States
City	Chicago
Period	16/06/19 → 21/06/19

Bibliographical note

Publisher Copyright:
© 2019 IEEE.

NLR Publication Number

NREL/CP-5K00-76322

Keywords

copper compounds
nanocrystals
photovoltaic cells
semiconductor materials
thin film devices

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Dippo, P., Kuciauskas, D., McClary, S., Li, S., Yin, X., Yan, Y., Baxter, J., & Agrawal, R. (2019). Optoelectronic Characterization of Emerging Solar Absorber Cu3AsS4. 2310-2314. Paper presented at 46th IEEE Photovoltaic Specialists Conference, PVSC 2019, Chicago, United States. https://doi.org/10.1109/PVSC40753.2019.8980590, https://doi.org/10.1109/PVSC40753.2019.8980590

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title = "Optoelectronic Characterization of Emerging Solar Absorber Cu3AsS4",

abstract = "Enargite Cu3AsS4 is a promising absorber for thin-film solar cells but little is known about its optoelectronic properties. Here, we present photoluminescence (PL) spectroscopy, time-resolved terahertz spectroscopy (TRTS), timeresolved photoluminescence (TRPL) spectroscopy, and cyclic voltammetry (CV) measurements of enargite thin films. The results indicate promising defect characteristics with minority carrier lifetimes on the order of ns, and band alignments suggest that buffer layers besides CdS must be developed to achieve high efficiency Cu3AsS4 solar cells.",

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author = "Patricia Dippo and Darius Kuciauskas and Scott McClary and Siming Li and Xinxing Yin and Yanfa Yan and Jason Baxter and Rakesh Agrawal",

note = "Publisher Copyright: {\textcopyright} 2019 IEEE.; 46th IEEE Photovoltaic Specialists Conference, PVSC 2019 ; Conference date: 16-06-2019 Through 21-06-2019",

year = "2019",

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doi = "10.1109/PVSC40753.2019.8980590",

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Dippo, P, Kuciauskas, D, McClary, S, Li, S, Yin, X, Yan, Y, Baxter, J & Agrawal, R 2019, 'Optoelectronic Characterization of Emerging Solar Absorber Cu3AsS4', Paper presented at 46th IEEE Photovoltaic Specialists Conference, PVSC 2019, Chicago, United States, 16/06/19 - 21/06/19 pp. 2310-2314. https://doi.org/10.1109/PVSC40753.2019.8980590, https://doi.org/10.1109/PVSC40753.2019.8980590

TY - CONF

T1 - Optoelectronic Characterization of Emerging Solar Absorber Cu3AsS4

AU - Dippo, Patricia

AU - Kuciauskas, Darius

AU - McClary, Scott

AU - Li, Siming

AU - Yin, Xinxing

AU - Yan, Yanfa

AU - Baxter, Jason

AU - Agrawal, Rakesh

PY - 2019/6

Y1 - 2019/6

N2 - Enargite Cu3AsS4 is a promising absorber for thin-film solar cells but little is known about its optoelectronic properties. Here, we present photoluminescence (PL) spectroscopy, time-resolved terahertz spectroscopy (TRTS), timeresolved photoluminescence (TRPL) spectroscopy, and cyclic voltammetry (CV) measurements of enargite thin films. The results indicate promising defect characteristics with minority carrier lifetimes on the order of ns, and band alignments suggest that buffer layers besides CdS must be developed to achieve high efficiency Cu3AsS4 solar cells.

AB - Enargite Cu3AsS4 is a promising absorber for thin-film solar cells but little is known about its optoelectronic properties. Here, we present photoluminescence (PL) spectroscopy, time-resolved terahertz spectroscopy (TRTS), timeresolved photoluminescence (TRPL) spectroscopy, and cyclic voltammetry (CV) measurements of enargite thin films. The results indicate promising defect characteristics with minority carrier lifetimes on the order of ns, and band alignments suggest that buffer layers besides CdS must be developed to achieve high efficiency Cu3AsS4 solar cells.

KW - copper compounds

KW - nanocrystals

KW - photovoltaic cells

KW - semiconductor materials

KW - thin film devices

UR - https://www.scopus.com/pages/publications/85081639455

U2 - 10.1109/PVSC40753.2019.8980590

DO - 10.1109/PVSC40753.2019.8980590

M3 - Paper

AN - SCOPUS:85081639455

SP - 2310

EP - 2314

T2 - 46th IEEE Photovoltaic Specialists Conference, PVSC 2019

Y2 - 16 June 2019 through 21 June 2019

ER -

Optoelectronic Characterization of Emerging Solar Absorber Cu3AsS4

Abstract

Conference

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Keywords

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