Non-Aqueous Thermolytic Route to Oxynitride Photomaterials using Molecular Precursors Ti(OtBu)4 and N[triple bond]Mo(OtBu)3

Daniel A. Ruddy; Obadiah G. Reid; Brian M. Leonard; Svitlana Pylypenko; Nathan R. Neale

doi:10.1039/C3TA13317F

Non-Aqueous Thermolytic Route to Oxynitride Photomaterials using Molecular Precursors Ti(OtBu)4 and N[triple bond]Mo(OtBu)3

Daniel A. Ruddy
, Obadiah G. Reid
, Brian M. Leonard
, Svitlana Pylypenko
, Nathan R. Neale

National Renewable Energy Laboratory
University of Wyoming
Colorado School of Mines

Research output: Contribution to journal › Article › peer-review

2 Scopus Citations

Abstract

Thermolytic decomposition of NMo(O^tBu)₃ with Ti(O^tBu)₄ results in mixed-metal oxynitrides that retain 75% of the N from the nitrido precursor. The fundamental photophysics of the oxynitrides were investigated, and TRMC measurements determined that Mo and N are critical to the long charge carrier lifetimes in the microsecond regime.

Original language	American English
Pages (from-to)	14066-14070
Number of pages	5
Journal	Journal of Materials Chemistry A
Volume	1
Issue number	45
DOIs	https://doi.org/10.1039/C3TA13317F https://doi.org/10.1039/c3ta13317f
State	Published - 7 Dec 2013

NLR Publication Number

NREL/JA-5900-60233

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title = "Non-Aqueous Thermolytic Route to Oxynitride Photomaterials using Molecular Precursors Ti(OtBu)4 and N[triple bond]Mo(OtBu)3",

abstract = "Thermolytic decomposition of NMo(OtBu)3 with Ti(OtBu)4 results in mixed-metal oxynitrides that retain 75\% of the N from the nitrido precursor. The fundamental photophysics of the oxynitrides were investigated, and TRMC measurements determined that Mo and N are critical to the long charge carrier lifetimes in the microsecond regime.",

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language = "American English",

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AU - Ruddy, Daniel A.

AU - Reid, Obadiah G.

AU - Leonard, Brian M.

AU - Pylypenko, Svitlana

AU - Neale, Nathan R.

PY - 2013/12/7

Y1 - 2013/12/7

N2 - Thermolytic decomposition of NMo(OtBu)3 with Ti(OtBu)4 results in mixed-metal oxynitrides that retain 75% of the N from the nitrido precursor. The fundamental photophysics of the oxynitrides were investigated, and TRMC measurements determined that Mo and N are critical to the long charge carrier lifetimes in the microsecond regime.

AB - Thermolytic decomposition of NMo(OtBu)3 with Ti(OtBu)4 results in mixed-metal oxynitrides that retain 75% of the N from the nitrido precursor. The fundamental photophysics of the oxynitrides were investigated, and TRMC measurements determined that Mo and N are critical to the long charge carrier lifetimes in the microsecond regime.

UR - https://www.scopus.com/pages/publications/84886855254

U2 - 10.1039/C3TA13317F

DO - 10.1039/C3TA13317F

M3 - Article

AN - SCOPUS:84886855254

SN - 2050-7488

VL - 1

SP - 14066

EP - 14070

JO - Journal of Materials Chemistry A

JF - Journal of Materials Chemistry A

IS - 45

ER -

Non-Aqueous Thermolytic Route to Oxynitride Photomaterials using Molecular Precursors Ti(OtBu)4 and N[triple bond]Mo(OtBu)3

Abstract

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